Formula sheets, the key method steps for every topic and 14 practice problems, with full solutions at the back.
8 g of Na and 64 g of Cl2 react according to 2Na + Cl2 → 2NaCl. What mass m of NaCl can form?
In the reaction 2Na + Cl2 → 2NaCl, 4 g of Na reacts completely (the other reactants are in excess) and 9.25 g of NaCl is collected. Find the percent yield Y.
You need 250 mL of 0.05 mol/L solution and have a 5 mol/L stock solution. What volume V1 of stock solution do you need?
100 mL of a 0.2 mol/L solution is mixed with 50 mL of a 0.1 mol/L solution of the same substance. Find the concentration c of the mixture (volumes are additive).
What volume V does 90 g of CH₄ occupy at 100 kPa and 100 °C? Treat it as an ideal gas.
A fixed amount of CH₄ goes from 100 kPa, 5 L, 35 °C to 300 kPa and 100 °C. Find the new volume V2.
A 200 g block of zinc (c = 0.388 J/(g·°C)) at 150 °C is dropped into 100 g of water (c = 4.18 J/(g·°C)) at 20 °C in an insulated cup. Find the final temperature Tf.
Use the standard enthalpies of formation to find the heat q released when 20 g of C3H8 (M = 44.1 g/mol) burns completely: C3H8 + 5O₂ → 3CO₂ + 4H₂O(l). Give q as a positive number.
0.1 mol/L of H₂ and 0.1 mol/L of I₂ are put in a container and react: H₂ + I₂ ⇌ 2HI, with Kc = 4. Find the equilibrium concentration [H2].
PCl₅ decomposes: PCl₅ ⇌ PCl₃ + Cl₂, with Kc = 0.2 at the reaction temperature. A container starts with 0.4 mol/L of PCl₅ only. Find the equilibrium concentration [PCl5].
Find the pH pH of a 0.01 mol/L solution of hydrofluoric acid (Ka = 0.00068).
A 1.00 L buffer contains 0.3 mol benzoic acid and 0.15 mol of its conjugate base (Ka = 6.3 × 10⁻⁵). 0.025 mol of NaOH is added. Find the new pH pH.
A first-order reaction in a batch reactor has k = 0.2 min⁻¹. How long does it take to reach 75% conversion? Find t.
A reaction has a rate constant of 0.02 min⁻¹ at 30 °C and an activation energy of 50 kJ/mol. Find the rate constant k2 at 60 °C.
Answer: m = 20.34 g
Stoichiometry: a balanced equation counts particles, not grams. Convert mass to moles with n = m/M, use the coefficients of the equation as the mole ratio, then convert back with m = n·M. With two reactants, the limiting reactant is the one that runs out first and fixes how much product forms.
Answer: Y = 90.97 %
Stoichiometry: a balanced equation counts particles, not grams. Convert mass to moles with n = m/M, use the coefficients of the equation as the mole ratio, then convert back with m = n·M. With two reactants, the limiting reactant is the one that runs out first and fixes how much product forms.
Answer: V1 = 2.5 mL
Molarity: concentration c = n/V in mol/L, with n = m/M. Diluting adds solvent but not solute, so the number of moles stays the same: c₁·V₁ = c₂·V₂. When two solutions of the same solute are mixed, the moles add up and so do the volumes.
Answer: c = 0.1667 mol/L
Molarity: concentration c = n/V in mol/L, with n = m/M. Diluting adds solvent but not solute, so the number of moles stays the same: c₁·V₁ = c₂·V₂. When two solutions of the same solute are mixed, the moles add up and so do the volumes.
Answer: V = 174.1 L
Ideal gas law: PV = nRT, with n = m/M.
Answer: V2 = 2.018 L
Combined gas law: for a fixed amount of ideal gas, P1V1/T1 = P2V2/T2.
Answer: Tf = 40.36 °C
Heat and enthalpy: heating a substance takes q = m·c·ΔT. In a calorimeter the heat lost by the hot object equals the heat gained by the cold one. The enthalpy change of a reaction follows from enthalpies of formation: ΔH° = ΣΔH°f(products) − ΣΔH°f(reactants), each multiplied by its coefficient.
Answer: q = 1007 kJ
Heat and enthalpy: heating a substance takes q = m·c·ΔT. In a calorimeter the heat lost by the hot object equals the heat gained by the cold one. The enthalpy change of a reaction follows from enthalpies of formation: ΔH° = ΣΔH°f(products) − ΣΔH°f(reactants), each multiplied by its coefficient.
Answer: [H2] = 0.05 mol/L
Chemical equilibrium: for aA + bB ⇌ cC + dD, the equilibrium constant is Kc = [C]c[D]d/([A]a[B]b), using concentrations at equilibrium. An ICE table (Initial, Change, Equilibrium) links the starting amounts to the equilibrium amounts through one unknown x, scaled by the coefficients.
Answer: [PCl5] = 0.2 mol/L
Chemical equilibrium: for aA + bB ⇌ cC + dD, the equilibrium constant is Kc = [C]c[D]d/([A]a[B]b), using concentrations at equilibrium. An ICE table (Initial, Change, Equilibrium) links the starting amounts to the equilibrium amounts through one unknown x, scaled by the coefficients.
Answer: pH = 2.64
pH: pH = −log₁₀[H₃O⁺] and pOH = −log₁₀[OH⁻], with pH + pOH = 14 at 25 °C. Strong acids and bases ionise completely. A weak acid only partly: Ka = x²/(c − x), where x = [H₃O⁺]. A buffer of a weak acid and its conjugate base follows Henderson–Hasselbalch: pH = pKa + log([A⁻]/[HA]).
HA ⇌ H⁺ + A⁻: x mol/L of acid ionises.
Answer: pH = 4.004
pH: pH = −log₁₀[H₃O⁺] and pOH = −log₁₀[OH⁻], with pH + pOH = 14 at 25 °C. Strong acids and bases ionise completely. A weak acid only partly: Ka = x²/(c − x), where x = [H₃O⁺]. A buffer of a weak acid and its conjugate base follows Henderson–Hasselbalch: pH = pKa + log([A⁻]/[HA]).
Answer: t = 6.931 min
Reaction rates: for a first-order reaction −dC/dt = kC, so C = C₀·e−kt and the half-life ln 2/k does not depend on concentration. For a second-order reaction 1/C = 1/C₀ + kt. The rate constant rises with temperature following Arrhenius: k = A·e−Ea/(RT).
Answer: k2 = 0.1194 min⁻¹
Reaction rates: for a first-order reaction −dC/dt = kC, so C = C₀·e−kt and the half-life ln 2/k does not depend on concentration. For a second-order reaction 1/C = 1/C₀ + kt. The rate constant rises with temperature following Arrhenius: k = A·e−Ea/(RT).
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