Formula sheets, the key method steps for every topic and 14 practice problems, with full solutions at the back.
24 g of Na and 16 g of Cl2 react according to 2Na + Cl2 → 2NaCl. What mass m of NaCl can form?
In the reaction 2Na + Cl2 → 2NaCl, 30 g of Na reacts completely (the other reactants are in excess) and 62.53 g of NaCl is collected. Find the percent yield Y.
You need 200 mL of 0.5 mol/L solution and have a 2.5 mol/L stock solution. How much water Vwater do you add to the stock solution?
100 mL of a 1 mol/L solution is mixed with 250 mL of a 0.75 mol/L solution of the same substance. Find the concentration c of the mixture (volumes are additive).
What volume V does 150 g of Ar occupy at 500 kPa and 95 °C? Treat it as an ideal gas.
Find the density ρ of CH₄ at 500 kPa and 20 °C, treating it as an ideal gas.
A 75 g block of copper (c = 0.385 J/(g·°C)) at 90 °C is dropped into 400 g of water (c = 4.18 J/(g·°C)) at 17 °C in an insulated cup. Find the final temperature Tf.
Use the standard enthalpies of formation to find ΔH° for the reaction CH4 + 2O₂ → CO₂ + 2H₂O(l).
0.4 mol/L of H₂ and 0.4 mol/L of I₂ are put in a container and react: H₂ + I₂ ⇌ 2HI, with Kc = 54. Find the equilibrium concentration [HI].
PCl₅ decomposes: PCl₅ ⇌ PCl₃ + Cl₂, with Kc = 0.01 at the reaction temperature. A container starts with 1 mol/L of PCl₅ only. Find the equilibrium concentration [PCl5].
Find the pH pH of a 0.01 mol/L solution of hypochlorous acid (Ka = 3 × 10⁻⁸).
A buffer contains 0.4 mol/L hydrofluoric acid and 0.05 mol/L of its sodium salt. Ka = 0.00068. Find the pH pH of the buffer.
A first-order reaction in a batch reactor has k = 0.3 min⁻¹. How long does it take to reach 60% conversion? Find t.
A first-order reaction has k = 0.02 min⁻¹ at 25 °C and an activation energy of 70 kJ/mol. The batch reactor is now run at 55 °C for 20 min. Find the conversion X reached.
Answer: m = 26.38 g
Stoichiometry: a balanced equation counts particles, not grams. Convert mass to moles with n = m/M, use the coefficients of the equation as the mole ratio, then convert back with m = n·M. With two reactants, the limiting reactant is the one that runs out first and fixes how much product forms.
Answer: Y = 82 %
Stoichiometry: a balanced equation counts particles, not grams. Convert mass to moles with n = m/M, use the coefficients of the equation as the mole ratio, then convert back with m = n·M. With two reactants, the limiting reactant is the one that runs out first and fixes how much product forms.
Answer: Vwater = 160 mL
Molarity: concentration c = n/V in mol/L, with n = m/M. Diluting adds solvent but not solute, so the number of moles stays the same: c₁·V₁ = c₂·V₂. When two solutions of the same solute are mixed, the moles add up and so do the volumes.
Answer: c = 0.8214 mol/L
Molarity: concentration c = n/V in mol/L, with n = m/M. Diluting adds solvent but not solute, so the number of moles stays the same: c₁·V₁ = c₂·V₂. When two solutions of the same solute are mixed, the moles add up and so do the volumes.
Answer: V = 22.98 L
Ideal gas law: PV = nRT, with n = m/M.
Answer: ρ = 3.291 kg/m³
Ideal gas density: ρ = PM/(RT).
Answer: Tf = 18.24 °C
Heat and enthalpy: heating a substance takes q = m·c·ΔT. In a calorimeter the heat lost by the hot object equals the heat gained by the cold one. The enthalpy change of a reaction follows from enthalpies of formation: ΔH° = ΣΔH°f(products) − ΣΔH°f(reactants), each multiplied by its coefficient.
Answer: ΔH° = −890.3 kJ
Heat and enthalpy: heating a substance takes q = m·c·ΔT. In a calorimeter the heat lost by the hot object equals the heat gained by the cold one. The enthalpy change of a reaction follows from enthalpies of formation: ΔH° = ΣΔH°f(products) − ΣΔH°f(reactants), each multiplied by its coefficient.
Negative: the reaction gives off heat (exothermic).
Answer: [HI] = 0.6288 mol/L
Chemical equilibrium: for aA + bB ⇌ cC + dD, the equilibrium constant is Kc = [C]c[D]d/([A]a[B]b), using concentrations at equilibrium. An ICE table (Initial, Change, Equilibrium) links the starting amounts to the equilibrium amounts through one unknown x, scaled by the coefficients.
Answer: [PCl5] = 0.9049 mol/L
Chemical equilibrium: for aA + bB ⇌ cC + dD, the equilibrium constant is Kc = [C]c[D]d/([A]a[B]b), using concentrations at equilibrium. An ICE table (Initial, Change, Equilibrium) links the starting amounts to the equilibrium amounts through one unknown x, scaled by the coefficients.
Answer: pH = 4.762
pH: pH = −log₁₀[H₃O⁺] and pOH = −log₁₀[OH⁻], with pH + pOH = 14 at 25 °C. Strong acids and bases ionise completely. A weak acid only partly: Ka = x²/(c − x), where x = [H₃O⁺]. A buffer of a weak acid and its conjugate base follows Henderson–Hasselbalch: pH = pKa + log([A⁻]/[HA]).
HA ⇌ H⁺ + A⁻: x mol/L of acid ionises.
Answer: pH = 2.264
pH: pH = −log₁₀[H₃O⁺] and pOH = −log₁₀[OH⁻], with pH + pOH = 14 at 25 °C. Strong acids and bases ionise completely. A weak acid only partly: Ka = x²/(c − x), where x = [H₃O⁺]. A buffer of a weak acid and its conjugate base follows Henderson–Hasselbalch: pH = pKa + log([A⁻]/[HA]).
Answer: t = 3.054 min
Reaction rates: for a first-order reaction −dC/dt = kC, so C = C₀·e−kt and the half-life ln 2/k does not depend on concentration. For a second-order reaction 1/C = 1/C₀ + kt. The rate constant rises with temperature following Arrhenius: k = A·e−Ea/(RT).
Answer: X = 99.49 %
Reaction rates: for a first-order reaction −dC/dt = kC, so C = C₀·e−kt and the half-life ln 2/k does not depend on concentration. For a second-order reaction 1/C = 1/C₀ + kt. The rate constant rises with temperature following Arrhenius: k = A·e−Ea/(RT).
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