Material and Energy Balances: cram pack

Formula sheets, the key method steps for every topic and 8 practice problems, with full solutions at the back.

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1Formulas and methods

Mass balance

Steady state
in = out
Total balance
ṁ1 + ṁ2 = ṁ3
Component balance
ṁ1x1 + ṁ2x2 = ṁ3x3
Evaporator
F·xF = P·xP, W = F − P

Energy balance

Sensible heat
Q = ṁ·cp·ΔT
Latent heat
Q = ṁ·hfg
Mixing
ΣṁcpTin = ΣṁcpTout
Water
cp ≈ 4.18 kJ/(kg·K)

Ideal gas law

Ideal gas law
pV = nRT
Gas constant
R = 8.314 J/(mol·K)
Combined gas law
p1V1/T1 = p2V2/T2
Moles
n = m/M
Temperature
T[K] = T[°C] + 273.15

Stoichiometry

Moles
n = m/M
Concentration
c = n/V
Mole ratio
use the coefficients of the balanced equation
Limiting reactant
the one that runs out first
Percent yield
actual / theoretical × 100%

Method

  1. Write and balance the chemical equation.
  2. Convert the given mass to moles: n = m/M.
  3. Use the coefficients as the mole ratio to find the moles of the substance you want.
  4. Convert back to mass with m = n·M. With two reactants, find the limiting reactant first.

2Practice problems

1.Mass balanceMedium
MixerStream 1500 kg/h · 35% saltStream 2ṁ₂ = ? · 10% saltProduct15% salt

How much of stream 2 must be added each hour to stream 1 so that the blended product contains 15% salt? Find ṁ2.

ṁ1 = 500 kg/hx1 = 35 %x2 = 10 %x3 = 15 %
ṁ2 = kg/h
2.Mass balanceHard
EvaporatorFeed F1400 kg/h · 17% sugarProduct P30% sugarVapour W (pure water)W = ? kg/h

An evaporator concentrates a sugar solution by boiling off pure water. Find the water evaporated W in kg/h.

F = 1400 kg/hxF = 17 %xP = 30 %
W = kg/h
3.Energy balanceMedium
hot sidecold sidelight oil · 150 °C70 °Cwater · 10 °Ct = ? °C

Hot light oil cools water in a counter-flow heat exchanger with no heat loss. Find the water outlet temperature tout.

ṁh = 0.5 kg/scp,h = 2.1 kJ/(kg·K)Th: 150 → 70 °Cṁc = 1.5 kg/scp,c = 4.18 kJ/(kg·K)tin = 10 °C
tout = °C
4.Energy balanceHard
hot sidecold sidelight oil · 170 °C70 °Cwater · 10 °C85 °C · ṁ = ?5% lost

Hot light oil heats water in an exchanger that loses 5% of the heat released by the hot stream to the surroundings. Find the water flow rate ṁc needed.

ṁh = 1 kg/scp,h = 2.1 kJ/(kg·K)Th: 170 → 70 °Ct: 10 → 85 °Ccp,c = 4.18 kJ/(kg·K)loss = 5 %
ṁc = kg/s
5.Ideal gas lawMedium
20 g of ArV = 20 LT = 0 °CP = ?

A tank of 20 L contains 20 g of Ar at 0 °C. Treat it as an ideal gas and find the pressure P.

m = 20 gM = 39.95 g/molV = 20 LT = 0 °CR = 8.314 J/(mol·K)
P = kPa
6.Ideal gas lawHard
N₂, M = 28.01 g/molP = 600 kPaT = 110 °Cρ = ?

Find the density ρ of N₂ at 600 kPa and 110 °C, treating it as an ideal gas.

M = 28.01 g/molP = 600 kPaT = 110 °CR = 8.314 J/(mol·K)
ρ = kg/m³
7.StoichiometryMedium
m(X)n(X)n(NaCl)m(NaCl)÷ M(X)× 2/ν× M(NaCl)

16 g of Na and 20 g of Cl2 react according to 2Na + Cl2 → 2NaCl. What mass m of NaCl can form?

M(Na) = 22.99M(Cl2) = 70.9M(NaCl) = 58.44 g/mol
m = g
8.StoichiometryHard
m(CH4​)n(CH4​)n(H2​O)m(H2​O)÷ M(CH4​)× 2/1× M(H2​O)

In the reaction CH4 + 2O2 → CO2 + 2H2O, 30 g of CH4 reacts completely (the other reactants are in excess) and 55.27 g of H2O is collected. Find the percent yield Y.

M(CH4) = 16.04 g/molM(H2O) = 18.02 g/molactual: 55.27 g
Y = %

3Solutions

1.Mass balance

Answer: ṁ2 = 2000 kg/h

Steady-state mass balance: in = out for the total and for each component. Blending problems combine both.

Balances

Total: ṁ3 = ṁ1 + ṁ2
salt: ṁ1x1 + ṁ2x2 = (ṁ1 + ṁ2)x3

Solve for ṁ2

ṁ2 = ṁ1(x1 − x3)/(x3 − x2) = 500·(35 − 15)/(15 − 10) = 2000 kg/h

Answer

ṁ2 = 2000 kg/h
2.Mass balance

Answer: W = 606.7 kg/h

Tie component: a component that passes through unchanged in one stream (here the solute) links the flows directly. Then the total balance gives the rest.

Solute balance

F·xF = P·xP → P = 1400·17/30 = 793.3 kg/h

Total balance

W = F − P = 1400 − 793.3 = 606.7 kg/h

Answer

W = 606.7 kg/h
3.Energy balance

Answer: tout = 23.4 °C

Exchanger energy balance: with no losses, ṁhcp,h(Th,in − Th,out) = ṁccp,c(tout − tin).

Heat released by the hot stream

Q = 0.5·2.1·(150 − 70) = 84 kW

Heat picked up by the water

tout = tin + Q/(ṁccp,c) = 10 + 84/(1.5·4.18) = 23.4 °C

Answer

tout = 23.4 °C
4.Energy balance

Answer: ṁc = 0.6364 kg/s

Energy balance with losses: heat released = heat absorbed + heat lost.

Heat released

Qh = 1·2.1·(170 − 70) = 210 kW

Heat that reaches the water

Qc = (1 − 0.05)·210 = 199.5 kW

Water flow rate

ṁc = Qc/(cp,c·Δt) = 199.5/(4.18·75) = 0.6364 kg/s

Answer

ṁc = 0.6364 kg/s
5.Ideal gas law

Answer: P = 56.85 kPa

Ideal gas law: PV = nRT, with n = m/M.

Moles

n = m/M = 20/39.95 = 0.5006 mol
T = 0 + 273.15 = 273.1 K

Pressure

P = nRT/V = 0.5006·8.314·273.1/0.02 = 56.85 kPa

Answer

P = 56.85 kPa
6.Ideal gas law

Answer: ρ = 5.276 kg/m³

Ideal gas density: ρ = PM/(RT).

Rearrange the gas law

PV = (m/M)RT → ρ = m/V = PM/(RT)
T = 110 + 273.15 = 383.1 K

Density

ρ = 600·28.01/(8.314·383.1) = 5.276 kg/m³

Answer

ρ = 5.276 kg/m³
7.Stoichiometry

Answer: m = 32.97 g

Stoichiometry: a balanced equation counts particles, not grams. Convert mass to moles with n = m/M, use the coefficients of the equation as the mole ratio, then convert back with m = n·M. With two reactants, the limiting reactant is the one that runs out first and fixes how much product forms.

Moles of each reactant

n(Na) = 16/22.99 = 0.696 mol
n(Cl2) = 20/70.9 = 0.2821 mol

Limiting reactant

0.696/2 = 0.348, 0.2821/1 = 0.2821 → Cl2

Mass of product

n(NaCl) = 0.2821·2 = 0.5642 mol
m = 0.5642·58.44 = 32.97 g

Answer

m = 32.97 g
8.Stoichiometry

Answer: Y = 82 %

Stoichiometry: a balanced equation counts particles, not grams. Convert mass to moles with n = m/M, use the coefficients of the equation as the mole ratio, then convert back with m = n·M. With two reactants, the limiting reactant is the one that runs out first and fixes how much product forms.

Theoretical yield

n(CH4) = 30/16.04 = 1.87 mol
m = 1.87·2/1·18.02 = 67.41 g

Percent yield

Y = 55.27/67.41·100 = 82%

Answer

Y = 82%

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