Chemical equilibrium worksheet with answers

Free printable Chemical equilibrium worksheet: 6 problems from easy to exam level, with an answer key. Print it or save it as a PDF.

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1.Easy
2SO2​0.4mol/L+O2​0.1mol/L⇌2SO3​0.25mol/LKc​ = ?

For the reaction 2SO2 + O2 ⇌ 2SO3, the equilibrium concentrations are [SO2] = 0.4 mol/L, [O2] = 0.1 mol/L, [SO3] = 0.25 mol/L. Find the equilibrium constant Kc.

[SO2] = 0.4[O2] = 0.1[SO3] = 0.25
Kc =
2.Easy
PCl5​0.25mol/L⇌PCl3​0.08mol/L+Cl2​0.4mol/LKc​ = ?

For the reaction PCl5 ⇌ PCl3 + Cl2, the equilibrium concentrations are [PCl5] = 0.25 mol/L, [PCl3] = 0.08 mol/L, [Cl2] = 0.4 mol/L. Find the equilibrium constant Kc.

[PCl5] = 0.25[PCl3] = 0.08[Cl2] = 0.4
Kc =
3.Medium
H2​I2​HII0.250.250C−x−x+2xE0.25 − x0.25 − x2x

0.25 mol/L of H₂ and 0.25 mol/L of I₂ are put in a container and react: H₂ + I₂ ⇌ 2HI, with Kc = 36. Find the equilibrium concentration [H2].

[H₂]₀ = [I₂]₀ = 0.25 mol/LKc = 36
[H2] = mol/L
4.Medium
H2​I2​HII0.20.20C−x−x+2xE0.2 − x0.2 − x2x

0.2 mol/L of H₂ and 0.2 mol/L of I₂ are put in a container and react: H₂ + I₂ ⇌ 2HI, with Kc = 49. Find the equilibrium concentration [H2].

[H₂]₀ = [I₂]₀ = 0.2 mol/LKc = 49
[H2] = mol/L
5.Hard
PCl5​PCl3​Cl2​I0.200C−x+x+xE0.2 − xxx

PCl₅ decomposes: PCl₅ ⇌ PCl₃ + Cl₂, with Kc = 0.04 at the reaction temperature. A container starts with 0.2 mol/L of PCl₅ only. Find the equilibrium concentration [PCl5].

[PCl₅]₀ = 0.2 mol/LKc = 0.04
[PCl5] = mol/L
6.Hard
PCl5​PCl3​Cl2​I0.2500C−x+x+xE0.25 − xxx

PCl₅ decomposes: PCl₅ ⇌ PCl₃ + Cl₂, with Kc = 0.01 at the reaction temperature. A container starts with 0.25 mol/L of PCl₅ only. Find the equilibrium concentration [PCl5].

[PCl₅]₀ = 0.25 mol/LKc = 0.01
[PCl5] = mol/L

Answer key

  1. 1. Kc = 3.906
  2. 2. Kc = 0.128
  3. 3. [H2] = 0.0625 mol/L
  4. 4. [H2] = 0.04444 mol/L
  5. 5. [PCl5] = 0.1283 mol/L
  6. 6. [PCl5] = 0.2048 mol/L

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