Learn Chemistry for nursing entrance exams from scratch
1Atoms, ions and isotopes
An atom has a nucleus of protons (+) and neutrons (no charge), surrounded by electrons (−) with almost no mass.
- Atomic number = number of protons. It identifies the element.
- Mass number = protons + neutrons.
- A neutral atom has as many electrons as protons.
- Isotopes have the same protons but different neutrons (carbon-12, carbon-14).
- Ions have gained electrons (negative anions, Cl⁻) or lost them (positive cations, Na⁺).
neutrons = mass number − atomic number
Self-check An atom has 17 protons and a mass number of 35. How many neutrons does it have?
- 17
- 18
- 35
- 52
Answer: 18. Neutrons = 35 − 17 = 18. Adding the numbers (52) or repeating the proton count (17) are the usual slips.
2The periodic table and bonding
Elements are ordered by atomic number. Groups (columns) share the number of valence electrons and similar properties; periods are rows. Group 1 = alkali metals, group 17 = halogens, group 18 = noble gases (full shells, unreactive).
Metals are on the left: shiny, conductive, they lose electrons. Nonmetals are on the right and gain or share electrons. Across a period atoms get smaller and more electronegative; fluorine is the most electronegative element.
- Ionic bond: a metal gives electrons to a nonmetal (NaCl). High melting points; conducts when dissolved.
- Covalent bond: nonmetals share electron pairs (H₂O, CO₂). Unequal sharing makes it polar.
- Hydrogen bonds: attractions between molecules such as water; they explain water’s high boiling point.
Ionic formulas balance the charges: Ca²⁺ + 2 Cl⁻ → CaCl₂; 2 Al³⁺ + 3 O²⁻ → Al₂O₃.
Self-check Which pair of elements is most likely to form an ionic bond?
- Carbon and oxygen
- Hydrogen and hydrogen
- Nitrogen and hydrogen
- Sodium and chlorine
Answer: Sodium and chlorine. A reactive metal (Na) and a nonmetal (Cl) transfer an electron. The other pairs are nonmetals that share electrons in covalent bonds.
3States of matter and gases
Solids have a fixed shape and volume; liquids a fixed volume but no fixed shape; gases fill their container. Temperature measures the average kinetic energy of the particles.
Phase changes: melting, freezing, evaporation, condensation, sublimation (solid → gas) and deposition (gas → solid). During a phase change the temperature stays constant.
Gas laws (temperatures in kelvin):
Boyle: P₁V₁ = P₂V₂ Charles: V₁/T₁ = V₂/T₂
Self-check At constant temperature, a gas is squeezed to one third of its volume. What happens to its pressure?
- It doubles
- It falls to one third
- It stays the same
- It triples
Answer: It triples. P × V stays constant (Boyle’s law), so one third of the volume means three times the pressure.
4Solutions, acids and bases
A solution is a solute dissolved in a solvent. Water is polar and dissolves ionic and polar substances; oil (nonpolar) does not mix with it: “like dissolves like”.
molarity (M) = moles of solute ÷ litres of solution C₁V₁ = C₂V₂
The pH scale runs from 0 to 14: below 7 acidic, 7 neutral, above 7 basic. Each unit is a factor of 10, so pH 3 has 100 times more H⁺ than pH 5.
Acid + base → salt + water (neutralisation). Strong acids ionise completely (HCl); weak acids only partly (acetic acid). A buffer resists pH change; the bicarbonate buffer keeps blood near pH 7.4.
Self-check You dilute 50 mL of a 4 M solution to 200 mL. What is the new concentration?
- 0.25 M
- 1 M
- 16 M
- 4 M
Answer: 1 M. C₂ = 4 × 50/200 = 1 M: the volume grows four times, so the concentration falls four times. 16 M multiplies instead of divides.
5Reactions and stoichiometry
Balance an equation by changing coefficients, never the subscripts, until each element has the same number of atoms on both sides.
- Synthesis: A + B → AB. Decomposition: AB → A + B.
- Single replacement: A + BC → AC + B. Double replacement: AB + CD → AD + CB.
- Combustion: fuel + O₂ → CO₂ + H₂O. Neutralisation: acid + base → salt + water.
One mole is 6.02 × 10²³ particles. Molar mass is the sum of the atomic masses (H₂O = 18 g/mol). The path is mass → moles → mole ratio → moles → mass.
Oxidation is loss of electrons, reduction is gain (OIL RIG). Catalysts speed up reactions without being used up; heat, concentration and surface area also raise the rate.
Worked exampleHow many grams of water form when 4 g of H₂ burn in plenty of oxygen? (2H₂ + O₂ → 2H₂O; H₂ = 2 g/mol, H₂O = 18 g/mol)
14 g ÷ 2 g/mol = 2 mol H₂.
2H₂ : H₂O = 2 : 2 = 1 : 1, so 2 mol H₂O form.
6How exam questions look
- Easy (key terms and facts): subatomic particles, groups of the periodic table, bond types, states of matter, the pH scale, reaction types.
- Medium (applying the concepts): neutrons from the mass number, ionic formulas, gas behaviour, molarity and dilution, balancing simple equations, molar mass.
- Hard (cases and analysis): balancing combustion equations, grams to grams, limiting reactants, pH and [H⁺], average atomic mass, gas-law calculations and buffers.
Write units at every step; they show whether to multiply or divide.
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